THERMODYNAMIC STUDY OF CdCl2 IN 2-PROPANOL (5 MASS %) + WATER MIXTURE USING POTENTIOMETRY (CROSBI ID 626528)
Prilog sa skupa u zborniku | izvorni znanstveni rad | međunarodna recenzija
Podaci o odgovornosti
Tomaš, Renato ; Vrdoljak, Anđelka
engleski
THERMODYNAMIC STUDY OF CdCl2 IN 2-PROPANOL (5 MASS %) + WATER MIXTURE USING POTENTIOMETRY
The potential difference (pd) measurements (E) are reported for galvanic cell without liquid junction: Cd(Hg) (l, sat.)/CdCl2(b) in Z/AgCl(s)/Ag(s) at different temperatures and various CdCl2 molalities (b) in aqueous mixture of 2-propanol (containing 5 mass % 2-propanol). From these values and using literature data for stability constants of the chlorocadmium complexes, the values of the standard pd of the cell were obtained at each temperature. These values served to calculate the standard thermodynamic quantities for the cell reaction, and also mean molal activity coefficients of CdCl2. The corresponding thermodynamic results are discussed and compared with literature data.
thermodynamic properties ; cadmium chloride ; 2-propanol + water mixed solvent ; potentiometry
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Podaci o prilogu
41-49.
2015.
objavljeno
Podaci o matičnoj publikaciji
International Scientific and Professional Conference 15th Ružička days
Šubarić, Drago ; Jukić, Ante
Osijek : Zagreb: Josip Juraj Strossmayer University of Osijek, Faculty of Food Technology Osijek, Croatian Society of Chemical Engineers
978-953-6894-53-6
Podaci o skupu
15th Ružička days "TODAY SCIENCE – TOMMOROW INDUSTRY"
poster
11.09.2014-12.09.2014
Vukovar, Hrvatska