Defying Stereotypes with Nanodiamonds: Stable Primary Diamondoid Phosphines (CROSBI ID 232025)
Prilog u časopisu | izvorni znanstveni rad | međunarodna recenzija
Podaci o odgovornosti
Moncea, Oana ; Gunawan, Maria A. ; Poinsot, Didier ; Cattey, Hélène ; Becker, Jonathan ; Yurchenko, Raisa I. ; Butova, Ekaterina D. ; Hausmann, Heike ; Šekutor, Marina ; Fokin, Andrey A. ; Hierso, Jean-Cyrille ; Schreiner, Peter R.
engleski
Defying Stereotypes with Nanodiamonds: Stable Primary Diamondoid Phosphines
Direct unequal C−H bond difunctionalization of phosphorylated diamantane was achieved in high yield from the corresponding phosphonates. Reduction of the functionalized phosphonates provides access to novel primary and secondary alkyl/aryl diamantane phosphines. The prepared primary diamantyl phosphines are quite air stable compared to their adamantyl and especially alkyl or aryl analogues. This finding is corroborated by comparing the singly occupied molecular orbital energy levels of the corresponding phosphine radical cations obtained by density functional theory computations.
Nanodiamonds ; Diamondoid Phosphines ; diamantane ; adamantane ; adamantylphosphine
M.Š. would like to thank the Alexander-von-Humboldt Foundation for a Humboldt Research Fellowship for Postdoctoral Researchers.
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Podaci o izdanju
81 (19)
2016.
8759-8769
objavljeno
0022-3263
1520-6904
10.1021/acs.joc.6b01219