Rapid, clean and gram-scale synthesis of microporous functional materials via mechanochemistry (CROSBI ID 641797)
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Podaci o odgovornosti
Užarević, Krunoslav
engleski
Rapid, clean and gram-scale synthesis of microporous functional materials via mechanochemistry
Here we present the application of mechanochemical reactions, [3] i.e. reactions between solid reactants induced by mechanical force, for a rapid, green and room-temperature transformation of environmentally safe metal precursors, oxides or hydroxides into most relevant microporous MOFs, notably those from MOF-74[4] or zirconium-based MOFs of UiO[5] family. We show here how the milling quantitatively produces MOFs in gram quantities by using only catalytic amount of ‘green solvents’, such as methanol or water, yielding microporous products with catalytic properties comparable to those from conventional solvothermal procedures.
Bundesanstalt für Materialforschung und -prüfung (BAM)
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Podaci o prilogu
2016.
objavljeno
Podaci o matičnoj publikaciji
Podaci o skupu
Bundesanstalt für Materialforschung und -prüfung (BAM)
pozvano predavanje
17.08.2016-17.08.2016
Berlin, Njemačka