Mechanosynthesis of 4, 4'-bis(N, N-dimethylamino)-azobenzene and its dicyclopalladated complex (CROSBI ID 649960)
Prilog sa skupa u zborniku | sažetak izlaganja sa skupa | domaća recenzija
Podaci o odgovornosti
Bjelopetrović, Alen ; Barišić, Dajana ; Lukin, Stipe ; Halasz, Ivan ; Užarević, Krunoslav ; Juribašić Kulcsar, Marina ; Ćurić, Manda
engleski
Mechanosynthesis of 4, 4'-bis(N, N-dimethylamino)-azobenzene and its dicyclopalladated complex
During the last decades mechanochemical reactions have been established as a viable green-chemistry alternative to conventional solution chemistry and have thus far been employed for the synthesis of a large variety of compounds along with transition-metal catalysed C–H bond functionalization. Herein, we demonstrate the solid-state synthesis of azobenzene ligand and its dicyclopalladated complex via C-H bond activation by palladium(II) acetate, Pd(OAc)2, applying different mechanochemical methods. The direct insight into the reaction dynamics and formation mechanism of dicyclopalladated complex in the solid state have been studied by in situ and ex situ monitoring using Raman and NMR spectroscopies, respectively.
cyclopalladation ; mechanochemistry ; azobenzene ; acetate
nije evidentirano
nije evidentirano
nije evidentirano
nije evidentirano
nije evidentirano
nije evidentirano
Podaci o prilogu
62-62.
2017.
objavljeno
Podaci o matičnoj publikaciji
Solid-State Science & Research : Book of Abstracts and Programme
Juribašić Kulcsar, Marina ; Halasz, Ivan
Zagreb: Institut Ruđer Bošković
978-953-7941-15-4
Podaci o skupu
Solid-State Science & Research Meeting
poster
28.07.2017-30.07.2017
Zagreb, Hrvatska