Nitranilic acid - a novel ligand for construction of coordination polymers (CROSBI ID 650954)
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Podaci o odgovornosti
Milašinović, Valentina ; Molčanov, Krešimir
engleski
Nitranilic acid - a novel ligand for construction of coordination polymers
Nitranilic acid (2, 5-dihydroxy-3, 5-dinitroquinone, NA) is a quinoid compound capable of acting as a bridging bis(bidentate) ligand. However, it has been surprisingly little studied and only a few of its metal complexes have been known. We have prepared and structurally characterised four novel coordination polymers of nitranilic acid with different topologies. Compounds [CoNA(H2O)2]n and [CuNA(H2O)2]n are isostructural and are 1D zig-zag polymers analogous to similar complexes of chloranilic acid. Anionic polymer [AgNA]-n crystallises as a salt with dimethylammonium cation and displays a novel 1D motive of double chains. Complex [Ag2NA]n has a 3D network. This study shows that the nitranilic acid has a great potential for design of coordination polymers or metal-organic frameworks.
Nitranilic acid ; coordination polymers
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Podaci o prilogu
76-76.
2017.
objavljeno
Podaci o matičnoj publikaciji
Twenty-fifth Slovenian-Croatian Crystallographic Meeting : Book of Abstracts and Programme
Podaci o skupu
Twenty-fifth Slovenian-Croatian Crystallographic Meeting
predavanje
14.06.2017-18.06.2017
Ljubljana, Slovenija