Cis- vs. trans- square-planar palladium(II) and platinum(II) complexes with triphenylphosphine amino acid bioconjugates (CROSBI ID 242063)
Prilog u časopisu | izvorni znanstveni rad | međunarodna recenzija
Podaci o odgovornosti
Kokan, Zoran ; Perić, Berislav ; Kovačević, Goran ; Brozovic, Anamaria ; Metzler-Nolte, Nils ; Kirin, Srećko I.
engleski
Cis- vs. trans- square-planar palladium(II) and platinum(II) complexes with triphenylphosphine amino acid bioconjugates
Triphenylphosphine–amino acid bioconjugates Ph2P-pC6H4-Aa-OR [Lig ; Aa = glycine (1G), alanine (2A), valine (3V), isoleucine (4I), proline (5P), or phenylalanine (6F)] were synthesized and used as monodentate ligands for the preparation of twelve metal complexes, [MCl2(Lig)2] (M = PdII or PtII). All of the prepared compounds were characterized by spectroscopic methods, and the structures of ligand 1G and complexes 1GPd, 4IPd, and 6FPd were determined by X-ray single-crystal diffraction. The cis and trans configurations of the square-planar metal complexes were investigated by solution NMR spectroscopy and computational methods.
Palladium ; Platinum ; Phosphine ligands ; Amino acids ; Biological activity
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Podaci o izdanju
2017 (33)
2017.
3928-3937
objavljeno
1434-1948
1099-0682
10.1002/ejic.201700679
Povezanost rada
Kemija