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izvor podataka: crosbi

Cis- vs. trans- square-planar palladium(II) and platinum(II) complexes with triphenylphosphine amino acid bioconjugates (CROSBI ID 242063)

Prilog u časopisu | izvorni znanstveni rad | međunarodna recenzija

Kokan, Zoran ; Perić, Berislav ; Kovačević, Goran ; Brozovic, Anamaria ; Metzler-Nolte, Nils ; Kirin, Srećko I. Cis- vs. trans- square-planar palladium(II) and platinum(II) complexes with triphenylphosphine amino acid bioconjugates // European journal of inorganic chemistry, 2017 (2017), 33; 3928-3937. doi: 10.1002/ejic.201700679

Podaci o odgovornosti

Kokan, Zoran ; Perić, Berislav ; Kovačević, Goran ; Brozovic, Anamaria ; Metzler-Nolte, Nils ; Kirin, Srećko I.

engleski

Cis- vs. trans- square-planar palladium(II) and platinum(II) complexes with triphenylphosphine amino acid bioconjugates

Triphenylphosphine–amino acid bioconjugates Ph2P-pC6H4-Aa-OR [Lig ; Aa = glycine (1G), alanine (2A), valine (3V), isoleucine (4I), proline (5P), or phenylalanine (6F)] were synthesized and used as monodentate ligands for the preparation of twelve metal complexes, [MCl2(Lig)2] (M = PdII or PtII). All of the prepared compounds were characterized by spectroscopic methods, and the structures of ligand 1G and complexes 1GPd, 4IPd, and 6FPd were determined by X-ray single-crystal diffraction. The cis and trans configurations of the square-planar metal complexes were investigated by solution NMR spectroscopy and computational methods.

Palladium ; Platinum ; Phosphine ligands ; Amino acids ; Biological activity

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Podaci o izdanju

2017 (33)

2017.

3928-3937

objavljeno

1434-1948

1099-0682

10.1002/ejic.201700679

Povezanost rada

Kemija

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