engleski

Synergistic effects during co-pyrolysis of biomass and plastic: gas, tar, soot, char products and thermogravimetric study

Synergistic effects of biomass and plastic co- pyrolysis on gas, tar, soot and char production and pyrolysis kinetics were studied using a fixed-bed reactor and a thermogravimetric analyzer, respectively. These pyrolysis products’ yields and compositions were measured during the individual pyrolysis of biomass and plastic at 800-1100 °C, and synergistic effects were explored under non-sooty (900 °C) and sooty (1100 °C) conditions. Results shows that the soot starts to form from tar at 900-1000 °C for both biomass and plastic and that the soot from plastic pyrolysis is of greater yield and size than the biomass pyrolysis. Under non- sooty conditions, the synergistic effect of co- pyrolysis results in higher char yields but lower tar yields, while under sooty conditions co- pyrolysis inhibits the gas and soot formation, resulting in higher tar yields and different soot morphologies. The synergistic effect observed by the thermogravimetric analysis agrees with that in a fixed-bed reactor.

Plastic ; biomass ; co-pyrolysis ; synergistic effect ; tar ; soot

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