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Cooperativity in Binding of Aliphatic Diamines by Bis(Zn(II)porphyrin) Receptor with Moderately Flexible Linkers (CROSBI ID 251012)

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Briš, Anamarija ; Trošelj, Pavle ; Margetić, Davor Cooperativity in Binding of Aliphatic Diamines by Bis(Zn(II)porphyrin) Receptor with Moderately Flexible Linkers // Croatica chemica acta, 90 (2017), 4; 667-677. doi: 10.5562/cca3249

Podaci o odgovornosti

Briš, Anamarija ; Trošelj, Pavle ; Margetić, Davor

engleski

Cooperativity in Binding of Aliphatic Diamines by Bis(Zn(II)porphyrin) Receptor with Moderately Flexible Linkers

Complexations of bis(Zn(II)porphyrin) receptor possessing moderately flexible linkers with aliphatic α, ω-diamines was studied by UV-vis and NMR spectroscopy. The strongest binding was identified for 1, 8-diaminooctane, with the binding constant by one order of the magnitude larger than the next diamine homologue 1, 7-diaminoheptane.

host-guest interactions ; supramolecular chemistry ; bis-porphyrin ; complexation ; binding constant ; UV-Vis

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Podaci o izdanju

90 (4)

2017.

667-677

objavljeno

0011-1643

1334-417X

10.5562/cca3249

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Kemija

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