Cooperativity in Binding of Aliphatic Diamines by Bis(Zn(II)porphyrin) Receptor with Moderately Flexible Linkers (CROSBI ID 251012)
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Briš, Anamarija ; Trošelj, Pavle ; Margetić, Davor
engleski
Cooperativity in Binding of Aliphatic Diamines by Bis(Zn(II)porphyrin) Receptor with Moderately Flexible Linkers
Complexations of bis(Zn(II)porphyrin) receptor possessing moderately flexible linkers with aliphatic α, ω-diamines was studied by UV-vis and NMR spectroscopy. The strongest binding was identified for 1, 8-diaminooctane, with the binding constant by one order of the magnitude larger than the next diamine homologue 1, 7-diaminoheptane.
host-guest interactions ; supramolecular chemistry ; bis-porphyrin ; complexation ; binding constant ; UV-Vis
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