Fluorescent Phenanthridine-Based Calix[4]arene Derivatives: Synthesis and Complexation Properties (CROSBI ID 667697)
Prilog sa skupa u časopisu | sažetak izlaganja sa skupa | međunarodna recenzija
Podaci o odgovornosti
Leko, Katarina ; Usenik, Andrea ; Cindro, Nikola ; Tomišić Vladislav
engleski
Fluorescent Phenanthridine-Based Calix[4]arene Derivatives: Synthesis and Complexation Properties
Calixarenes are macrocyclic oligomers consisted of four or more phenolic residues linked by methylene groups in the ortho position and can be easily functionalized to give receptors for vast number of ionic or neutral species. Calixarenes bearing fluorescent moieties can be considered as potentially very sensitive fluorimetric ion sensors due to the high sensitivity of fluorescence spectroscopy and high affinity of these macrocyclic ligands towards cations. In the scope of this work, two novel fluorescent phenathridine-based calix[4]arene derivatives were designed and prepared. The binding affinities of these compounds towards metal cations in several solvents (acetonitrile, methanol, ethanol, N, N-dimethylformamide, dimethylsufoxide) were investigated. Phenanthridine moities were introduced at a lower calix[4]arene rim and served both as fluorescent probes and parts of cation-binding site. Stability constants of the corresponding complexes were determined by means of UV spectrophotometry, fluorimetry and isothermal microcalorimetry. The latter technique also provided information on reaction enthalpies and entropies. The obtained results were discussed regarding the structural characteristics of the calixarene derivatives and differences in solvation abilities of the solvents used.
calix[4]arenes ; phenantridine ; metal cations ; fluorescence ; complexation ; thermodynamics
Special Issue of Bulletin of the Chemists and Technologists of Bosnia and Herzegovina
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Podaci o prilogu
111-111.
2018.
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objavljeno
Podaci o matičnoj publikaciji
Glasnik hemičara i tehnologa Bosne i Hercegovine = Bulletin of the Chemists and Technologists of Bosnia and Herzegovina
Korać, Fehim
Sarajevo:
0367-4444
2232-7266
Podaci o skupu
3rd International Congress of Chemists and Chemical Engineers of Bosnia and Herzegovina
poster
19.10.2018-21.10.2018
Sarajevo, Bosna i Hercegovina
Povezanost rada
Kemija