New Mononuclear Iron Complex: Synthesis, X-Ray Diffraction, Magnetization, X-Band and High-Field ESR Study (CROSBI ID 668860)
Prilog sa skupa u zborniku | sažetak izlaganja sa skupa | međunarodna recenzija
Podaci o odgovornosti
Muratović, Senada ; Žilić, Dijana ; Džolić, Zoran ; Cetina, Mario ; Pajić, Damir ; Krupskaya, Yulia ; Kataev, Vladislav ; Goriya, Yogesh ; Johnson, Magnus
engleski
New Mononuclear Iron Complex: Synthesis, X-Ray Diffraction, Magnetization, X-Band and High-Field ESR Study
Reaction of 2-hydroxy-6-methylpyridine (L) with iron(II) tetrafluoroborate results in the isolation of [FeL6](BF4)3 a mononuclear iron(III) octahedral complex. X -ray diffraction studies have confirmed the existence of iron (III). Polycrystalline sample of the complex has been investigated by X-ray diffraction, magnetization and electron spin resonance (HF-ESR) spectroscopy. Beside commercially available X-band ESR, we used also multi-frequency (up to 318 GHz) high-field (up to 16 T) HF-ESR spectroscopy (Fig. 1). The obtained results will be discussed in terms of magneto-structural correlations. [1, 2] [1] P. Gamez et al. Dalton Trans. 2009, 7845-7853 [2] L. Wang et al. Chem. Eur. J. 10.1002/chem.201705989
Iron complex ; ESR spectroscopy ; High-field
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Podaci o prilogu
125-125.
2018.
objavljeno
Podaci o matičnoj publikaciji
ECMolS 2018 - 2nd European Conference on Molecular Spintronics
Peníscola:
Podaci o skupu
2nd European Conference on Molecular Spintronics
poster
21.10.2018-24.10.2018
Peníscola, Španjolska