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Pregled bibliografske jedinice broj: 11247

Časopis

Autori: Radić, Njegomir; Komljenović, Josipa
Naslov: Determination of N-acetyl-cysteine by flow-injection potentiometry
Izvornik: Fresenius journal of analytical chemistry (0937-0633) 360 (1998), 6; 675-678
Vrsta rada: članak
Ključne riječi: flow-injection potentiometry, tubular sensor, N-acetylcysteine
Sažetak:
A multi-purpose tubular flow-through sensor was constructed with an AgI-based membrane. The membrane was prepared by pressing silver salts (AgI, Ag_2S) and powdered Teflon. This membrane was incorporated in the tubular flow-through sensor body. A 2-mm diameter hole was drilled through the center of the tubular sensor and the membrane, thus determining the active sensor volume of about 4 microL. The tubular sensor with reference electrode was placed into a complex flow-injection sy! stem and used for the flow-through determination of N-acetyl-L-cysteine, (NAC), in perchloric acid medium, pH=1. Linear dependence was established between the recorded signal height and the concentration of NAC in the injected sample. The recorded change in potential for a decade change in concentration, 62 mV {;p(NAC)};^-1, in the concentration range from 1×10^-4 to 1×10^-1 M, was based on the formation mechanism of the sparingly soluble deposit between silver and NAC on the surface of the sensitive part of the membrane.
Projekt / tema: 011005
Izvorni jezik: ENG
Current Contents: DA
Citation Index: DA
Kategorija: Znanstveni
Znanstvena područja:
Kemija
Tiskani medij: da
URL Internet adrese: http://www.springerlink.com/content/21m859g6r7ex42qn/fulltext.pdf
DOI: 10.1007/s002160050779



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