engleski

The effect of the electrolyte concentration in the solution on the voltammetric response of insertion electrodes

A solid-state redox reaction involving an insertation of ions is analyzed with respect to the influence of the concentration of inserting ions in the solution phase. The voltammetric response is independent of the mass transfer in the solution provided that the parameter z is smaller than 0.1. In the real cases this condition will be satisfied at solution concentration above 1 mol/L.

insertion electrode; cyclic voltammetry; electrolyte concentration; mass transport; solid-state electrochemistry

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