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Adamantane-dipyrromethanes: novel anion receptors (CROSBI ID 134005)

Prilog u časopisu | izvorni znanstveni rad | međunarodna recenzija

Renić, Marija ; Basarić, Nikola ; Mlinarić-Majerski, Kata Adamantane-dipyrromethanes: novel anion receptors // Tetrahedron letters, 48 (2007), 44; 7873-7877-x

Podaci o odgovornosti

Renić, Marija ; Basarić, Nikola ; Mlinarić-Majerski, Kata

engleski

Adamantane-dipyrromethanes: novel anion receptors

New adamantane-dipyrromethanes (AdD 1-4) were synthesized and their anion binding properties investigated. AdD 1-3 form 2:1 complexes with F- (AdD:F=2:1) characterized by high association constants, and 1:1 complexes with Cl-, Br-, HSO4- and H2PO4-. The binding of Cl-, Br-, HSO4- and H2PO4- by AdD 1-3 is 2-3 times stronger than for the reference compound, meso-phenyldipyrromethane (5). However, AdD 4 forms complexes with F- characterized by 1:1 and 1:2 stoichiometry (AdD:F = 1:2).

adamantane-dipyrromethanes; anion binding; NMR titration; pyrroles; synthesis

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Podaci o izdanju

48 (44)

2007.

7873-7877-x

objavljeno

0040-4039

Povezanost rada

Kemija

Indeksiranost