Hrvatska znanstvena bibliografija (CROSBI)



Pregled bibliografske jedinice broj: 365483

Časopis

Autori: Basarić, Nikola; Horvat, Margareta; Mlinarić-Majerski, Kata; Zimmermann, Elmar; Neudörfl, Jörg; Griesbeck, Axel G.
Naslov: Novel 2, 4-Methanoadamantane-Benzazepine by a Domino Photochemistry of N-(1-adamantyl)phthalimide
Izvornik: Organic Letters (1523-7060) 10 (2008), 18; 3965-3968
Vrsta rada: članak
Ključne riječi: 2; 4-methanoadamantane-benzazepine; N-(1-adamantyl)phthalimide; domino phothochemistry
Sažetak:
The photochemical reaction of N-(1-adamantyl)phthalimide (1) gives cleanly one product, the novel hexacyclic benzazepine derivative of 2, 4-methanoadamantane 2. Its structure was characterized by spectroscopic methods and X-ray analysis and represent the first example of the 2-azahexacyclo[8.7.1.11, 4.04, 9.011, 16.012, 18]nonadeca-4, 6, 8-triene skeleton. The product is formed by a domino process of two consecutive excited state intramolecular hydrogen transfer reactions. Base hydrolysis of the benzazepine 2 gives in high yield the keto derivative of the 1, 2-substituted adamantane ε -amino acid 3.
Projekt / tema: 098-0982933-2911
Izvorni jezik: ENG
Rad je indeksiran u
bazama podataka:
Current Contents Connect (CCC)
MEDLINE
Scopus
SCI-EXP, SSCI i/ili A&HCI
Science Citation Index Expanded (SCI-EXP) (sastavni dio Web of Science Core Collectiona)
Kategorija: Znanstveni
Znanstvena područja:
Kemija
URL Internet adrese: http://pubs.acs.org/doi/pdf/10.1021/ol801362x
http://pubs.acs.org/doi/abs/10.1021/ol801362x
Broj citata:
Altmetric:
DOI: 10.1021/ol801362x
URL cjelovitog teksta:
Google Scholar: Novel 2, 4-Methanoadamantane-Benzazepine by a Domino Photochemistry of N-(1-adamantyl)phthalimide
Upisao u CROSBI: eluksa@irb.hr (eluksa@irb.hr), 16. Ruj. 2008. u 14:29 sati