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Pregled bibliografske jedinice broj: 375658

Časopis

Autori: Basarić, Nikola; Horvat, Margareta; Franković, Oliver; Mlinarić-Majerski, Kata; Neudörfl, Jörg; Griesbeck, Axel G.
Naslov: Photoinduced hydrogen atom abstraction in N-(adamantyl)phthalimides: Structure-Reactivity Study in the Solid State
Izvornik: Tetrahedron (0040-4020) 65 (2009), 7; 1438-1443
Vrsta rada: članak
Ključne riječi: adamantane phthalimides; photoinduced H abstraction; solid state photochemistry; X-ray analysis
Sažetak:
Adamantyl-functionalized phthalimides were synthesized and the probability of intramolecular photochemical hydrogen atom abstraction in the solid-state analyzed by X-ray crystallographic analyses. These analyses and solid-state photolyses showed that the parameters determining photochemical reactivity for typical carbonyl compounds in the solid state can also be extended to phthalimides. Only N-(2-adamantyl)phthalimide underwent a solid state photochemical reaction, which is the first example in the phthalimide series. This reaction is regio- and stereoselective, resulting in an endo-alcohol. On the other hand, the photoreaction of N-(2-adamantyl)phthalimide in solution gives an exo-alcohol as the main product together with an endo-alcohol and a benzazepindione.
Projekt / tema: 098-0982933-2911
Izvorni jezik: ENG
Rad je indeksiran u
bazama podataka:
Current Contents Connect (CCC)
Scopus
SCI-EXP, SSCI i/ili A&HCI
Science Citation Index Expanded (SCI-EXP) (sastavni dio Web of Science Core Collectiona)
Kategorija: Znanstveni
Znanstvena područja:
Kemija
URL Internet adrese: http://dx.doi.org/10.1016/j.tet.2008.12.010
http:///www.sciencedirect.com/science?_ob=MImg&_imagekey=B6THR-4V42J49-6-D&_cdi=5289&_user=3875467&_orig=search&_coverDate=02%2F14%2F2009&_sk=999349992&view=c&wchp=dGLbVtz-zSkWb&md5=4c9916d0e2b8e31fd32e578ea817e720&ie=/sdarticle.pdf
Broj citata:
Altmetric:
DOI: 10.1016/j.tet.2008.10.010
URL cjelovitog teksta:
Google Scholar: Photoinduced hydrogen atom abstraction in N-(adamantyl)phthalimides: Structure-Reactivity Study in the Solid State
Upisao u CROSBI: eluksa@irb.hr (eluksa@irb.hr), 15. Pro. 2008. u 12:32 sati



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