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Pregled bibliografske jedinice broj: 444489

Zbornik radova

Autori: Horvat, Margareta; Basarić, Nikola; Mlinarić-Majerski, Kata; Griesbeck, Axel G.
Naslov: Photodecarboxylative addition of 3-phthalimidoadamantane-1-carboxylic acid to alkenes
Izvornik: Central European Conference on Photochemstry - CECP 2010, Bad Hofgastein, Austria
Skup: Central European Conference on Photochemstry - CECP 2010
Mjesto i datum: Bad Hofgastein, Austria, 7-11.02.2010.
Ključne riječi: Induced reaction; Phthalimides; Photodecarboxylation
Sažetak:
Within the scope of our research on synthesis of novel adamantane derivatives, we turned our attention to photochemistry of phthalimides as convenient method for the preparation of complex polycyclic structures [1]. In continuation of that research we focused on photodecarboxylation of phthalimides as a powerful synthetic method for intermolecular alkylations [2] and arylations [3].Herein, we report on photochemistry of 3-phthalimidoadamantane-1-carboxylic acid (1) and its photoinduced decarboxylative addition to double bonds. This novel photodecarboxylation induced reaction could serve as a simple synthetic method for a C-C bond formation and preparation of more complex adamantane derivatives such as 3. The probable mechanism supported by time-resolved LFP measurements will be discussed.
Vrsta sudjelovanja: Poster
Vrsta prezentacije u zborniku: Sažetak
Vrsta recenzije: Međunarodna recenzija
Projekt / tema: 098-0982933-2911
Izvorni jezik: ENG
Kategorija: Znanstveni
Znanstvena područja:
Kemija
Upisao u CROSBI: eluksa@irb.hr (eluksa@irb.hr), 16. Vel. 2010. u 09:51 sati



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