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Pregled bibliografske jedinice broj: 504685

Časopis

Autori: Cindro, Nikola; Horvat, Margareta; Mlinarić-Majerski, Kata; Griesbeck, Axel G.; Basarić, Nikola
Naslov: Photoinduced homolytic C–H activation in N-(4-homoadamantyl)phthalimide
Izvornik: Beilstein journal of organic chemistry (1860-5397) 7 (2011); 270-277
Vrsta rada: članak
Ključne riječi: homoadamantanes ; photoinduced H-abstraction ; phthalimides
Sažetak:
N-(4-homoadamantyl)phthalimide (5) on excitation and population of the triplet excited state underwent intramolecular H-abstractions and gave products 6 and 7. The major product, exo-alcohol 6 was a result of the regioselective δ H-abstraction and the stereoselective cyclization of the 1, 5-biradical. Minor products 7 were formed by photoinduced γ H-abstractions, followed by ring closure to azetidinols and ring enlargement to azepinediones. The observed selectivity to exo-alcohol 6 was explained by the conformation of 5 and the best orientation and the availability of the δ-H for the abstraction.
Projekt / tema: 098-0982933-2911, 02.05/25
Izvorni jezik: ENG
Rad je indeksiran u
bazama podataka:
Current Contents Connect (CCC)
Scopus
SCI-EXP, SSCI i/ili A&HCI
Science Citation Index Expanded (SCI-EXP) (sastavni dio Web of Science Core Collectiona)
Kategorija: Znanstveni
Znanstvena područja:
Kemija
URL Internet adrese: https://www.beilstein-journals.org/bjoc/articles/7/36
http://www.beilstein-journals.org/bjoc/content/pdf/1860-5397-7-36.pdf
Broj citata:
Altmetric:
DOI: 10.3762/bjoc.7.36
URL cjelovitog teksta:
Google Scholar: Photoinduced homolytic C–H activation in N-(4-homoadamantyl)phthalimide
Upisao u CROSBI: eluksa@irb.hr (eluksa@irb.hr), 3. Ožu. 2011. u 12:56 sati



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