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Pregled bibliografske jedinice broj: 672192

Poglavlje/Rad u knjizi

Autori: Dobovišek, Andrej; Županović, Paško; Brumen, Milan; Juretić, Davor
Naslov: Maximum Entropy Production and Maximum Shannon Entropy as Germane Principles for the Evolution of Enzyme Kinetics
Knjiga: Beyond the Second Law: Entropy Production and Non- equilibrium Systems
Urednik/ci: Dewar, Roderick C ; Charles ; Lineweaver, Charles H ; Niven, Robert K ; Regenauer-Lieb, Klaus
Izdavač: Springer-Verlag
Grad: Berlin
Godina: 2014
Serija: Understanding Complex Systems (Ed. S. Kelso)
Raspon stranica:: 361-382
Ukupni broj stranica u knjizi:: 435
ISBN: 978-3-642-40153-4
Ključne riječi: Maximum entropy production principle, Maximum information entropy principle, enzyme kinetics, evolution, photosynthesis, ATPase, Michaelis-Menten kinetics, bacteriorhodopsin
Sažetak:
There have been many attempts to use optimization approaches to study the biological evolution of enzyme kinetics. Our basic assumption here is that the biological evolution of catalytic cycle fluxes between enzyme internal functional states is accompanied by increased entropy production of the fluxes and increased Shannon information entropy of the states. We use simplified models of enzyme catalytic cycles and bioenergetically important free-energy transduction cycles to examine the extent to which this assumption agrees with experimental data. We also discuss the relevance of Prigogine’s minimal entropy production theorem to biological evolution.
Projekt / tema: 177-1770495-0476
Izvorni jezik: ENG
Kategorija: Znanstveni
Znanstvena područja:
Fizika,Kemija,Biologija
Upisao u CROSBI: Davor Juretić (juretic@pmfst.hr), 3. Sij. 2014. u 23:15 sati



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