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ELECTROCHEMISTRY OF COMPLEXED COPPER(II) AT SEAWATER CONCENTRATION LEVELS (CROSBI ID 481802)

Prilog sa skupa u zborniku | izvorni znanstveni rad | međunarodna recenzija

Cuculić, Vlado ; Branica, Marko ELECTROCHEMISTRY OF COMPLEXED COPPER(II) AT SEAWATER CONCENTRATION LEVELS // Rapport du 36e Congres de la CIESM / Fowler, Scott (ur.). Monte Carlo: CIESM, 2001. str. 118-118-x

Podaci o odgovornosti

Cuculić, Vlado ; Branica, Marko

engleski

ELECTROCHEMISTRY OF COMPLEXED COPPER(II) AT SEAWATER CONCENTRATION LEVELS

The electrochemical reactions of the copper(II)-salicylaldoxime complex (Cu(II)-SA) adsorbed onto mercury drop are influenced by the “neutral” buffer 4-(2-hydroxyethyl)-1-piperazineethanesulfonic acid (HEPES). The reduction currents of the Cu(II)-SA complex in 0.55 M NaCl and 0.7 M NaClO4 solutions increased by a factor of two in the presence of the HEPES (pH = 8.0), whereas the reduction potential shifted to more positive values. The weak adsorption of the HEPES onto mercury drop facilitates the electron transfer between the mercury electrode and the adsorbed Cu(II)-SA complex.

electrochemistry; trace elements; metals; copper(II)

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Podaci o prilogu

118-118-x.

2001.

objavljeno

Podaci o matičnoj publikaciji

Rapport du 36e Congres de la CIESM

Fowler, Scott

Monte Carlo: CIESM

Podaci o skupu

36e Congres de la CIESM

poster

24.09.2001-28.09.2001

Monte Carlo, Monako

Povezanost rada

Kemija