Nitrile Cluster Compounds [M_6X_12)X_2(RCN)_4] (M = Nb, Ta ; X = Cl, Br ; R = Et, n-Pr, n-Bu) (CROSBI ID 93775)
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Podaci o odgovornosti
Planinić, Pavica ; Rastija, Vesna ; Širac, Siniša ; Vojnović, Marija ; Frkanec, Leo ; Brničević, Nevenka ; McCarley, Robert E.
engleski
Nitrile Cluster Compounds [M_6X_12)X_2(RCN)_4] (M = Nb, Ta ; X = Cl, Br ; R = Et, n-Pr, n-Bu)
Three new series of mixed-ligand clusters of the [M_6X_12)X_2(RCN)_4] (M = Nb, Ta ; X = Cl, Br ; R = Et, n-Pr, n-Bu) composition have been prepared. It is supposed that four nitrile molecules and two halogene atoms are coordinated to the terminal octahedral coordination sites of the [M_6X_12]^2+ unit.
Hexanuclear niobium clusters; hexanuclear tantalum clusters; nitrile complexes; mixed-ligand complexes
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