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Extraction and complexation of alkali and alkaline earth metal cations by lower-rim calix[4]arene diethylene glycol amide derivatives (CROSBI ID 219128)

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Sviben, Igor ; Galić, Nives ; Tomišić, Vladislav ; Frkanec, Leo Extraction and complexation of alkali and alkaline earth metal cations by lower-rim calix[4]arene diethylene glycol amide derivatives // New journal of chemistry, 39 (2015), 6099-6107. doi: 10.1039/C5NJ00805K

Podaci o odgovornosti

Sviben, Igor ; Galić, Nives ; Tomišić, Vladislav ; Frkanec, Leo

engleski

Extraction and complexation of alkali and alkaline earth metal cations by lower-rim calix[4]arene diethylene glycol amide derivatives

Novel calix[4]arene derivatives, 5, 11, 17, 23- tetra-tert-butyl-25, 26, 27, 28-tetrakis(N-(2- (2- methoxyethoxy)ethyl)carbamoyl methoxy)calix[4]arene (1) and 5, 11, 17, 23- tetra- tert-butyl-25, 26, 27, 28-tetra(N, N- bis(2-(2- methoxyethoxy)ethyl)carbamoyl methoxy)calix[4]arene (2), were prepared by introducing diethylene glycol subunits at the lower calixarene rim. The complexation affinities of these compounds towards alkali and alkaline earth metal cations were studied at 25 °C in acetonitrile and methanol by means of spectrophotometric, conductometric, and potentiometric titrations. The stability constants of the corresponding complexes with 1 : 1 (cation : ligand) stoichiometry were determined (in some cases only estimated), and their values obtained by different methods were in good agreement. The complexes with secondary-amide derivative (1) were observed to have much lower stabilities than those with tertiary-amide derivative (2). This was presumably mostly caused by the presence of intramolecular NHO[double bond, length as m- dash]C hydrogen bonds in the former case. It was found that solvent significantly affected the stability of the complexes ; the prepared calixarenes showed considerably higher affinities for cations in acetonitrile than in methanol. Generally, the ligands studied showed better binding abilities for alkaline earth cations than for alkali metal cations. The extraction of metal picrates from water to dichloromethane by the complexation of metal ions with ligands 1 and 2 was also investigated. In accordance with the complex stabilities, all cations were extracted fairly well (in some cases even excellently) with the tertiary-amide derivative, whereas this was not the case in the extraction experiments with the other ligand studied.

calix[4]arene ; ethylene glycol ; complexation ; stability constant ; extraction

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Podaci o izdanju

39

2015.

6099-6107

objavljeno

1144-0546

1369-9261

10.1039/C5NJ00805K

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Kemija

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